Mechanism of Chromic Acid Oxidation of Acrylonitrile
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Chromic Acid Oxidation of Lactic Acid Catalysed by Manganese(II)
B ak o re and N a r a in 1 studied the kinetics of the oxidation of a-hydroxy acids by chromium(VI) and found that addition of Mn(II) decreases the rate of oxidation to one half of that in absence of Mn(II), when the hydrogen ion concentration is in the range 0.1 to 0.4 M. They attributed this to the disproportionation of Cr(IV) by Mn(II) ions. K em p and W a t e r s 2 observed Mn(II) catalysis...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1962
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.65.34